A microanalytical trace element and geochronological study wascarried out on mafic amphibole-rich cumulates (quartz diorites)cropping out in northern Victoria Land (Antarctica). Associatedtonalites and basement rocks were also investigated. Rock texturesand major and trace element mineral compositions reveal thepresence in quartz diorites of two mineral assemblages: (1)clinopyroxene-I + brown amphibole ± dark mica; (2) clinopyroxene-II+ green amphibole + plagioclase + quartz. Both mineral assemblagescontain mafic phases with elevated Mg-number, but their traceelement signatures differ significantly. In situ U–Pbzircon geochronology was carried out to support petrogeneticand geological interpretations. Quartz diorites were emplacedin the mid-crust probably at 516 ± 3 Ma. Parental meltsof quartz diorites were computed by applying solid/liquid partitioncoefficients. The melt in equilibrium with the first mineralassemblage (melt-I) is extremely depleted in heavy rare earthelements (HREE), Y, Ti, Zr and Hf (at about 0·2 timesnormal mid-ocean ridge basalt) and enriched in B, Th, U, thelarge ion lithophile elements and light REE (LREE). It sharesmany similarities with sanukitic melts (e.g. Setouchi andesites),which originated by equilibration of subduction-derived sedimentmelts with a refractory mantle. The melt in equilibrium withthe second mineral assemblage (melt-II) is characterized bya steep LREE enrichment (LaN/YbN up to 39), a U-shaped HREEpattern and low Ti, which is depleted relative to HREE. Thetrace element signature of melt-II can be acquired through amphibolecrystallization starting from a sanukitic melt similar to melt-I,probably in a deeper magma chamber. Our results allow us toconstrain that melts from the subducted slab were produced ona regional scale, in accordance with literature data, belowa large sector of the east Gondwana margin during the mid-Cambrian.Implications for the role of amphibole in petrogenesis of subduction-relatedmagmas are also discussed. KEY WORDS: amphibole; sanukite; high-Mg andesites; Ross Orogeny; Antarctica相似文献
Abstract. During the austral summer 1997–98, within the framework of the activities of the Climatic Long-term Interaction for the Massbalance in Antarctica (CLIMA) Project of the Italian National Program for Antarctic Research (PNRA) in the Ross Sea, measurements were conducted to focus on the role of dissolved iron, copper and manganese as micronutrients, and on their distribution in suspended particulate matter in different water masses. Sampling was carried out in two selected shelf areas, both important for formation and mixing processes of the water bodies. Metal data were evaluated together with physical measurements and classical chemical parameters such as oxygen and nutrients. In both the studied areas, the distribution of dissolved metals along the waste column confirmed their micronutrient behaviour, showing depletion where phytoplanktonic activities occurred. The trend of particulate metals underlined the scavenging phenomena along the water column and presented an interesting correlation at intermediate depths with the amount and origin of suspended matter. 相似文献
The Teplá–Barrandian unit (TBU) of the Bohemian Massif shared a common geological history throughout the Neoproterozoic and Cambrian with the Avalonian–Cadomian terranes. The Neoproterozoic evolution of an active plate margin in the Teplá–Barrandian is similar to Avalonian rocks in Newfoundland, whereas the Cambrian transtension and related calc-alkaline plutons are reminiscent of the Cadomian Ossa–Morena Zone and the Armorican Massif in western Europe. The Neoproterozoic evolution of the Teplá–Barrandian unit fits well with that of the Lausitz area (Saxothuringian unit), but is significantly distinct from the history of the Moravo–Silesian unit.The oldest volcanic activity in the Bohemian Massif is dated at 609+17/−19 Ma (U–Pb upper intercept). Subduction-related volcanic rocks have been dated from 585±7 to 568±3 Ma (lower intercept, rhyolite boulders), which pre-dates the age of sedimentation of the Cadomian flysch (
t
chovice Group). Accretion, uplift and erosion of the volcanic arc is documented by the Neoproterozoic Dob
í
conglomerate of the upper part of the flysch. The intrusion age of 541+7/−8 Ma from the Zgorzelec granodiorite is interpreted as a minimum age of the Neoproterozoic sequence. The Neoproterozoic crust was tilted and subsequently early Cambrian intrusions dated at 522±2 Ma (T
ovice granite), 524±3 Ma (V
epadly granodiorite), 523±3 Ma (Smr
ovice tonalite), 523±1 Ma (Smr
ovice gabbro) and 524±0.8 Ma (Orlovice gabbro) were emplaced into transtensive shear zones. 相似文献
The Gustav Group of the James Ross Basin, Antarctic Peninsula, forms part of a major Southern Hemisphere Cretaceous reference section. Palynological data, chiefly from dinoflagellate cysts, integrated with macrofaunal evidence and strontium isotope stratigraphy, indicate that the Gustav Group, which is approximately 2.6 km thick, is Aptian–Coniacian in age. Aptian–Coniacian palynofloras in the James Ross Basin closely resemble coeval associations from Australia and New Zealand, and Australian palynological zonation schemes are applicable to the Gustav Group. The lowermost units, the coeval Pedersen and Lagrelius Point formations, have both yielded early Aptian dinoflagellate cysts. Because the overlying Kotick Point Formation is of early to mid Albian age, the Aptian/Albian boundary is placed, questionably, at the Lagrelius Point Formation–Kotick Point Formation boundary on James Ross Island, and this transition may be unconformable. Although the Kotick Point Formation is largely early Albian on dinoflagellate cyst evidence, the uppermost part of the formation appears to be of mid Albian age. This differentiation of the early and mid Albian has refined the age of the formation, previously considered to be Aptian–Albian, based on macrofaunal evidence. The Whisky Bay Formation is of late Albian to latest Turonian age on dinoflagellate cyst evidence and this supports the macrofaunal ages. Late Albian palynofloras have been recorded from the Gin Cove, lower Tumbledown Cliffs, Bibby Point and the lower–middle Lewis Hill members. However, the Cenomanian age of the upper Tumbledown Cliffs and Rum Cove members, based on molluscan evidence, is not supported by the dinoflagellate cyst floras and further work is required on this succession. The uppermost part of the Whisky Bay Formation in north-west James Ross Island is of mid to late Turonian age and this is confirmed by strontium isotope stratigraphy. The uppermost unit, the Hidden Lake Formation, is Coniacian in age on both palaeontological and strontium isotope evidence. The uppermost part of the formation appears to be early Santonian based on dinoflagellate cysts, but strontium isotope stratigraphy constrains this as being no younger than late Coniacian. This refined palynostratigraphy greatly improves the potential of the James Ross Basin as a major Cretaceous Southern Hemisphere reference section. 相似文献
Remobilization of sandstones can dramatically reconfigure original depositional geometries and results in very unusually shaped sandstones, which resemble little, if any, of the original geometry. A number of deformational sandstone bodies, dykes and volcanoes from the upper part of the Carboniferous Ross Formation are described, which offer the opportunity to examine a suite of field-scale reconfigured sandstones. These structures are located in close proximity to the Ross Slide, which outcrops along a 2-km section on the northern coast of the Loop Head Peninsula, County Clare, Ireland. Dome- and ridge-shaped deformational sandstone bodies, dykes and volcanoes are interpreted to be the product of remobilization of a turbiditic sandstone. Liquification and remobilization were triggered by translation, cessation and loading of the underlying turbiditic sandstone by the Ross Slide. Deformational sand body, dyke and volcano development occurred in an asynchronous fashion with deformational sand bodies formed during slump translation. Sand dykes and volcanoes developed after the cessation of slump movement. During slump translation, the minimum principal stress (σ3) was orientated vertically and the slump behaved in a `ductile' manner. After slump arrest, the minimum principal stress was oriented horizontally, and the unit regained shear strength to behave in a `brittle' manner. The relative change in rheological states with changing applied shear stress is indicative of thixotropic-like behaviour within the slump mass. Ridge-shaped deformational sand bodies are aligned parallel to slump folds, and their morphology is inferred to be controlled by compressional slump deformation associated with heterogeneous cessation of slump movement that was initiated by frontal arrest of the translating mass. 相似文献
The U-Pb and Sm-Nd dating of deep crustal rocks from the Bergen Arcs system helps resolve enigmatic aspects of the tectonic evolution of the Caledonian Orogen in western Norway and yields insights into the arrested stages of eclogite development within the granulites of the area. The U-Pb dating of zircon from one of the eclogite facies shear zones yields an upper intercept age of 945 ± 5 Ma [all errors two standard deviations (2σ)], which is similar to other zircon ages from the granulite facies protolith. The age is interpreted to represent the time of late Proterozoic (Sveconorwegian) granulite metamorphism. The U-Pb ages of sphene and epidote show that the eclogites formed early in the evolution of the Caledonian Orogen (pre-Scandian phase) at about 460 Ma. An eclogite facies quartz vein yields a Sm-Nd whole rock-garnet isochron of 440 ± 12 Ma that may reflect the onset of cooling immediately after peak eclogite facies conditions, although the Sm-Nd systematics reveal some isotopic disequilibrium within the sample. In tandem with previous 40Ar/39Ar age determinations from, an adjacent eclogite of 450 Ma for hornblende and 430 Ma for muscovite, these data indicate that < 30 Ma elapsed between formation of the eclogites and the initial stages of cooling and exhumation to at least mid-crustal levels. This corresponds to minimum cooling rates of 14 °C/m.y. The timing relations suggest that the formation and exhumation of these eclogites from the overlying Caledonian Nappe wedge in western Norway are related to an early phase of crustal subduction during or somewhat before the major phase of continent-continent collision.
The short period of time between the formation of the eclogites and the initial stages of exhumation and rapid cooling is consistent with the only partial and localized transformation of the granulite to eclogite. Isolated occurrences of eclogite within the granulite, the formation of eclogite along metasomatic fronts and the formation of hydrous eclogite facies minerals within the “dry” granulite all point to the importance of fluids in the transformation and re-equilibration of the granulite to eclogite. Together, field and isotopic data demonstrate that both the localized and limited access of fluids and the rapid cycling of continental crust through the deepest portions of the orogen to upper crustal levels resulted in the preservation of the arrested stages of eclogite formation and survival of the granulites metastably through eclogite facies conditions. 相似文献
The O'okiep Copper District is underlain by voluminous 10351210Ma granite gneiss and granite with remnants of metamorphosedsupracrustal rocks. This assemblage was intruded by the 1030Ma copper-bearing Koperberg Suite that includes jotunite, anorthosite,biotite diorite and hypersthene-bearing rocks ranging from leuconoriteto hypersthenite. New sensitive high-resolution ion microprobeage data demonstrate the presence of 17002000 Ma zirconas xenocrysts in all of the intrusive rocks, and as detritalzircon in the metasediments of the Khurisberg Subgroup. Thesedata are consistent with published SmNd model ages ofc. 1700 Ma (TCHUR) and c. 2000 Ma (TDM) of many of the intrusivesthat support a major crust-forming event in Eburnian (Hudsonian)times. In addition, UThPb analyses of zirconsfrom all major rock units define two tectono-magmatic episodesof the Namaquan Orogeny: (1) the O'okiepian Episode (11801210Ma), represented by regional granite plutonism, notably theNababeep and Modderfontein Granite Gneisses and the Concordiaand Kweekfontein Granites that accompanied and outlasted (e.g.Kweekfontein Granite) regional tectonism [F2(D2)] and granulite-faciesmetamorphism (M2); (2) the Klondikean Episode (10201040Ma), which includes the intrusion of the porphyritic RietbergGranite and of the Koperberg Suite that are devoid of regionalplanar or linear fabrics. Klondikean tectonism (D3) is reflectedby major eastwest-trending open folds [F3(D3a)], andby localized eastwest-trending near-vertical ductilefolds [steep structures; F4(D3b)] whose formationwas broadly coeval with the intrusion of the Koperberg Suite.A regional, largely thermal, amphibolite- to granulite-faciesmetamorphism (M3) accompanied D3. This study demonstrates, interalia, that the complete spectrum of rock-types of the KoperbergSuite, together with the Rietberg Granite, was intruded in ashort time-interval (<10 Myr) at c. 1030 Ma, and that therewere lengthy periods of about 150 Myr of tectonic quiescencewithin the Namaquan Orogeny: (1) between the O'okiepian andKlondikean Episodes; (2) from the end of the latter to the formalend of Namaquan Orogenesis 800850 Ma ago. KEY WORDS: UPb, zircon; O'okiep, Namaqualand; granite plutonism; granulite facies; Koperberg Suite; Namaquan (Grenville) Orogeny相似文献
In pre-drift reconstructions, the central and southern parts of the Borborema Province, northeastern Brazil, belong to a large Brasiliano-Pan-African orogenic realm situated to the north of the São Francisco-Congo Craton. In order to better understand the timing and geodynamic setting under which this orogenic system developed, a structural, geochemical and geochronological study was conducted across the east Pernambuco shear zone (EPSZ) system, which separates the Pernambuco-Alagoas Domain (PEAL) from the Central Domain. A sample of the Pinhões orthogneiss (GE-1), in the Central Domain, one sample of a syenitic orthogneiss (CA-34) wrapped by the EPSZ, and one sample of orthogneiss named Altinho (CA-40), in the northern portion of the PEAL, were dated by LA-ICP-MS. The Pinhões orthogneiss yielded an age of 869 ± 9 Ma, interpreted as the emplacement age of the protolith during a late Tonian magmatic episode. Samples CA-40 and CA-34 yielded 206Pb/238U weighted mean ages of 652 ± 6 Ma and 636 ± 3 Ma, respectively, which are interpreted as dating emplacement and crystallization of the magmatic protoliths. However, it is also possible that these rocks were formed during the same magmatic event in view of the identical ages of 646 ± 13 Ma and 646 ± 11 Ma, respectively, given by the less precise upper intercept of the discordia lines. The metaluminous and magnesian nature of the Altinho orthogneiss is akin to the calc-alkalic suite. However, some samples plot in the intraplate field in tectonic discrimination diagrams and the Nd TDM model age of 1.36 Ga is unlike that of juvenile magmas in convergent settings. The Altinho orthogneiss is quite similar in terms of trace elements geochemistry to the syenitic orthogneiss, which has a clearer intraplate affinity, and the dated samples have identical initial Sr isotope ratios (0.7047). Therefore, emplacement in an extensional setting is preferred over a convergent one. Two samples of paragneisses (SB-1 and BB-9) from the PEAL were also dated. The ages of the youngest zircon grains in sample BB-9 (655–642 Ma) overlap the crystallization age of the Altinho orthogneiss, implying that sedimentation is younger than or, at best, synchronous with magmatism. The age of low Th/U grains in samples CA-34 (615 ± 8 Ma) and SB-1 (587 ± 12 Ma) are related to a subsequent metamorphic overprint, which is loosely constrained between 580 and 620 Ma. These observations, combined with evidence provided by previous studies, suggest that the change from an extensional to a contracional setting occurred at ca. 640–630 Ma. In contrast with most collisional orogens, where a long period of oceanic subduction precedes collision, the inferred tectonic evolution suggests that the Brasiliano Orogeny resulted from inversion of continental and/or proto oceanic rifts. 相似文献